Free energy functional for nonequilibrium systems: an exactly solvable case.

نویسندگان

  • B Derrida
  • J L Lebowitz
  • E R Speer
چکیده

We consider the steady state of an open system in which there is a flux of matter between two reservoirs at different chemical potentials. For a large system of size N, the probability of any macroscopic density profile rho(x) is exp[-NF([rho])]; F thus generalizes to nonequilibrium systems the notion of free energy density for equilibrium systems. Our exact expression for F is a nonlocal functional of rho, which yields the macroscopically long range correlations in the nonequilibrium steady state previously predicted by fluctuating hydrodynamics and observed experimentally.

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عنوان ژورنال:
  • Physical review letters

دوره 87 15  شماره 

صفحات  -

تاریخ انتشار 2001